The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogen oxides / Br oxides / BrOOBr / Mauldin(1993)_220K_290-360nm

DATAFILE: BrOOBr_Mauldin(1993)_220K_290-360nm.txt
NAME: dibromine dioxide, bromine monoxide dimer, bromine peroxide
FORMULA: BrOOBr
AUTHOR(YEAR): Mauldin(1993)
T: 220K
λ: 290-360nm
BIBLIOGRAPHY: R.L. Mauldin III, A. Wahner, and A.R. Ravishankara, "Kinetics and mechanism of the self-reaction of the BrO radical", J. Phys. Chem. 97, 7585-7596 (1993) DOI: 10.1021/j100131a031
COMMENTS: A flash photolysis-long path absorption technique was used to study the self-reaction of BrO radicals

An additional absorption feature with a peak absorption at 312 nm was observed at 220 K and was tentatively attributed to BrOOBr

Absorption cross sections plotted in Fig. 9 of

M.H. Harwood, D.M. Rowley, R.A. Cox, and R.L. Jones, "Kinetics and mechanism of the BrO self-reaction: Temperature- and pressure-dependent studies", J. Phys. Chem. A 102, 1790-1802, 1998; DOI: 10.1021/jp973264p

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